Captain America uses his shield like a frisbee, and he always sticks his hand out to catch it. Would it be possible for him to accidentally catch Mjolnir instead?

It would be logical that Steve Rogers is worthy of wielding Mjolnir, but if Thor and Steve are together in battle, is it logical that Steve would be able to catch Mjolnir even when its owner is nearby?

Is there any canonical evidence referencing this?