Absolutely
The Disney canon novelization Beware the Power of the Dark Side! makes this very clear. Not only is Luke using the dark side when he defeats Vader, he’s employing it throughout the scenes in the throne room.
To start with, the Emperor is described as "bringing out Luke’s own dark side."
“Your friends up there on the forest moon are walking into a trap. As
is your rebel fleet! It was I who allowed the Alliance to know the
location of the shield generator. It is quite safe from your pitiful
little band. An entire legion of my best troops awaits them.”
Now the fear in Luke’s heart grows—they are doomed! And the fear
quickly turns to anger. He whirls back to face the Emperor but his
gaze lands on his weapon. Oh, how quickly the Emperor has brought out
Luke’s own dark side! And now to push him just a little further….
Beware the Power of the Dark Side!
Luke is explicitly described as employing the dark side against Vader. Indeed, he only is winning because of the dark side:
He falls and Luke is preparing to leap down after him when he hears
the Emperor behind him.
“Good. Use your aggressive feelings, boy. Let the hate flow through
you.” Again, the Emperor is telling the truth and Luke knows it. He
has won, but only by using the dark side of the Force. The hate is
flowing through him and he is winning this battle against his father
because of it.
Beware the Power of the Dark Side!
Later, when Vader taunts Luke about Leia turning to the dark side:
“Sister! So…you have a twin sister. Obi-Wan was wise to hide her from
me. But now his failure is complete. Your feelings have betrayed her,
too. If you will not turn to the dark side, perhaps she will.”
“Never!” screams Luke, launching himself out of the gloom, lightsaber
blazing, fighting as he has never fought before. He swings wildly,
madly, using the dark side to move faster and strike harder. He has
felt anger and hate before, but never this much fear…fear for his
sister, Leia.
Beware the Power of the Dark Side!
Of the Sith trinity (anger, fear, and hatred) Luke is particularly employing fear here.
So Luke definitely employs the dark side. It’s part of his temptation by the Emperor. But, unlike his father, Luke rejects this power: As George Lucas says:
So that isn’t what the Emperor had in mind. He wanted this really
super guy, but that got derailed by Obi-Wan. So he finds that, with
Luke, he can get a more primo version if he can turn Luke to the Dark
Side. You’ll see, as this goes on, Luke is faced with the same issues
and practically the same scenes that Anakin is faced with. Anakin says
yes and Luke says no.