First, "if Vibranium is indestructible, how was Captain America's shield created (melting and hammering shouldn't work)?" type questions should be trivial. the answer would be similar to that of Adamantium: Just after extraction, it can be moulded just once. The shape would be permanent after that.
(If answer is different for Vibranium, let me know)
But, in Avengers: Age of Ultron movie,
Vibranium was used to create Vision's muscular body. Ultron took Vibranium rods from black market and later we saw that Vibranium was combining well with biological artificial tissues.
Now, the question is: How is such application of Vibranium possible if Vibranium is indestructible? Why is Captain America's shield, supposedly, indestructible?