Is this The Cure for Passion...?
Asha the potion maker remembers everything about her tragic past life, including her former husband, Karligo. They were in a seemingly loveless marriage that constantly left Asha feeling lonely and unfulfilled because Karligo would never even look at her, let alone touch her. But in this life, Asha has met a drastically changed Karligo! Now that he's afflicted with uncontrollable desire and feverish lust, can Asha cure him before his fiery passion burns them both?
A blonde duchess named Rena spent five years in a loveless marriage with her black-haired husband, Karligo Edmund, before they were accused of being rebels and killed by knights sent by the Emperor.
Rena subsequently wakes up in the world of a novel she'd read as Asha Bliss, a potion maker with her own shop. Asha is summoned to the manor of Archduke Karligo Aetus, the male lead of the novel who's notorious for being a tyrant and a philanderer. When she meets him though, she immediately recognises him as her dead former husband, since they both look the same as they did in their previous lives. She's wearing a hooded cloak, however, and that, combined with dim lighting, is apparently enough to prevent him from recognising her.
Karligo wants Asha to make him a potion to supress his sexual desires, and she thinks to herself how uncomfortable it must be for him to be trapped in the body of a lustful playboy, when he was so sexually restrained in his previous life that they never actually consummated their marriage.
You can read the full manhwa at Tapas.