The known General Orders (along with other regulations and guidelines) are listed on both Memory Alpha and Memory Beta:
General Order 1: "No starship may interfere with the normal development of any alien life or society." (TAS: "The Magicks of Megas-Tu")
General Order 4: Said to be the only death penalty left on the books. (TOS: "Turnabout Intruder")
General Order 6: If all life aboard a Federation starship had perished, the ship would self-destruct within twenty-four hours to protect other ships from potential hazards within. (TAS: "Albatross")
General Order 7: No vessel under any condition, emergency or otherwise, is to visit Talos IV.
General Order 12: On the approach of any vessel, when communications have not been established... (Star Trek II: The Wrath of Khan)
General Order 13: Evacuation Order for Starfleet vessels. (Star Trek)
General Order 15: No flag officer shall beam into a hazardous area without armed escort. (Star Trek II: The Wrath of Khan)
General Order 24: An order to destroy all life on an entire planet. This order has been given by Captain Garth (Antos IV) and Captain Kirk (Eminiar VII). On neither occasion was the order actually fulfilled. (TOS: "Whom Gods Destroy", "A Taste of Armageddon")
https://memory-alpha.fandom.com/wiki/General_Orders
http://memory-beta.wikia.com/wiki/General_Orders